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The Hamiltonian of the harmonic oscillator
 |
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(2.6) |
can be re-written using the ladder operators
as
 |
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(2.9) |
The commutation relation is
![$\displaystyle [\hat{x},\hat{p}]=i\hbar,\quad [a,a^{\dagger}]=1.$](img1451.png) |
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(2.10) |
The eigenfunctions of the harmonic oscillator are
-phonon states,
where
are the Hermite polynomials.
The ladder operators are also called creation (
) and annihiliation
operators. They act on the states
as
 |
|
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(2.12) |
The state
is called ground state.
Next: Pure Vibrational Dipole Transitions
Up: Pure Vibration
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Tobias Brandes
2005-04-26